This is not windows\temp_avast_ folder, it’s AppData\Local\Temp_avast_\unpF05C.tmp… so the TMP file doesn’t come from AvastSvc, but rather from something running under the user’s account. Weird… I find it unlikely that AvastUI would create such files; maybe a browser or an email client (where Avast plugin does something)?

Is the file recent (so you may be able to guess if you have done anything unusual… special web pages with streaming content, something like that), or is it old?