The one good thing is that the avastSvc.exe is running that is the main avast service/process and handles all of the scanning/shields, etc. The avastUI.exe it the user interface providing access to the user interface and settings, it doesn’t have a security function.

What happens if you double click on the C:\Program Files\AVAST Software\Avast\AvastUI.exe file ?

Since this is a User based function (not System), something may be blocking it, which may become apparent when you try to run it.