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I was watching this thread on the MS Forums … It seems to come down to the Avast! Toolbar and its services.
http://answers.microsoft.com/en-us/ie/forum/ie10-windows_7/internet-explorer-wont-access-hotmail/df182561-4776-48f3-97ef-f8717b4920a2
Right clicking on the Avast! Toolbar Icon in Windows 8 (64bit) / Internet Explorer 10 to Disable the Avast! Toolbar worked and I can use my Hotmail. (Merci, John). Doing so indicated that the services listed would be disabled. The list was composed of multiple ( three ) instances of “avast! Online Security” . I am wondering if the service is reloading multiple time and getting confused or consuming multiple resources? Nonetheless, it appears to be a avast! issue so I will switching over to their support site. Thanks All !
NOTE: Using the Avast! SafeZone option is also a workaround for now.