If the scan completed successfully (not found anything - depending on your scan settings) it would normally boot into windows.

Look in the C:\Documents and Settings\All Users\Application Data\Avast Software\Avast\report\aswBoot.txt file (XP location) C:\ProgramData\Avast Software\Avast\report\aswBoot.txt (Vista, Win7 and later location), check this file using notepad for info on the scan/detections, etc.