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Nothing will happen if the user stops Avast temporarily only to print then re-ables it. I highly doubt the user will run into a piece of malware within the matter of a few seconds. Its not that easy to be infected. If it wasn’t meant to be stops then they wouldn’t provide that functionality. What other Chrome Addons are you using? Also which version of Chrome? Latest version of Chrome is 28.0.1.500.72. If Avast was blocking it then it should be in your Avast logs. But I am sure its not. Are you using something like NoScript or ScriptNo? There are no settings in Avast which would stop a printer from printing. If you can print a test page and print from IE then its not Avast. It maybe a conflict of an Addon.