I’ve posted a SHA1SUM of the .dll in question.
I’ve also added that the .dll in question, has been registered the same date !avast free was installed, to which you reply again, that this is not part of the normal !avast free installation, suspecting this .dll is malicious I’ll proceed to a complete uninstallation and re-installation of !avast free and keep detailed installation logs which I will post back here.

A screenshot of what?
There are numerous settings for e-mail protection in !avast’s settings.
Namely in: Settings → Active Protection → E-mail Shield.

Is it possible that you could supply a SHA1SUM of your .dll or at least could you confirm it matches the one I’ve posted?