There are also comments about this (related problem) and links to other topics. This is one of them https://forum.avast.com/index.php?topic=320643.0 there are others but this one also shows how to disable this new function.
There has just been a new program update 22.8 but that has yet to be announced in the forums, so no information on any features or fixes, etc.
This begs the question what Avast version do you currently have installed ?
I think moving to using the Windows Recovery Environment for the Boot-Time scan is a definite step forward, than the pre-historic method before (even if I’m unlikely to use it, other than for testing). However with many different OS versions, I asked the question about compatible OSes in that topic, but so far no response.
In another topic Avast has received a support file and is investigating, also support page to be updated:
So for the moment it is disable using the Windows RE boot-time scan in the geek:area, awaiting a fix and using the old method, or stop using the boot-time scan for now.