Well, i guess i will call my bank and tell them to put a stop on the payment.
Hey all, I just checked my email and found some good news! I received a response from Avast regarding the support ticket I sent to sales. It said that they were looking into the problem and that something went wrong with the order because the purchase went through, but the license file didn’t automatically generate. Several hours later I was sent an Order Confirmation again from Digital River, this time with the License filed attached! Yay! 
I inserted the License File, and now I’m good to go! Hopefully you all will have your License Files waiting for you in your inbox - if not, I suggest sending a support ticket. Best Wishes!
Great. Be sure to file that license away. Just to be sure, I burned it to a few CDs and put them in a safe place.
Yes, on my hard drive, also.