You appear to have an undetected trojan spambot on your system avast doesn’t have the function to block for specific accounts, it is quite possible it isn’t even using your email proram to send the email.
I would suggest that you put this in the Viruses and Worms Forum, but a forum search in that forum is sure to bring up similar topics as it is one that if frequently encountered.
I suggest that you schedule a boot time scanning with avast. Start avast! > Right click the skin > Schedule a boot-time scanning. Select for scanning archives. Boot.
Also, it will be good if you download, install, update and run other trojan remover tools: a-squared and/or Free AVG Antispyware (trojan removers). Some users recommend SUPERantispyware or Spyware Terminator.
Also, if you still detecting strange behaviors or you want to be sure you’re clean, maybe making a HijackThis log to post here and, specially, scan and submit to on-line analysis the RunScanner log would help to identify the problem and the solution.
Disable System Restore on Windows ME or Windows XP. System Restore cannot be disabled on Windows 9x and it’s not available in Windows 2k. After boot you can enable System Restore again.
Schedule a boot time scanning with avast. Start avast! > Right click the skin > Schedule a boot-time scanning. Select for scanning archives. Boot. Other option is scanning in SafeMode (repeatedly press F8 while booting).
I sort of understand the allure of writing a virus that can’t be detected (sort of like hacking) but I wonder if they worry about the troubles they put people through.
The allure is money, sending out the spam in the hope that some fool will think, ‘oh I really need that, insert product of choice here.’ Instead of ‘never’ buy anything from unsolicited email (just delete spam), if no one bought then it wouldn’t be worth doing.