If you remove ashMaiSv.exe from the allowed applications to connect the Internet and try to get email again, will your firewall ask for permission? Will it work, i.e., you can receive mail?
While I usually use Thunderbird, I tried Outlook Express to get a better error message.
Here it is (in German - sorry):
Is this correct? You’re using 85.13.1xx.1yy at port 110?