You can send the file to virus@avast.com
But, your avast installation is more up-to-date than the virustotal one.
Maybe it’s not a false positive but the signature was added recently.
Why do you think it is an FP, if just because avast doesn’t detect it on VT, think again.
It isn’t unusual to not have avast detect on VirusTotal when it does so on your system. VT isn’t able to update the VPS in real time as the user is and this is often the cause. Remember the point of submitting it to VT is to see what the other scanners find.
What was the malware name and location of the infected file detected on your system ?
I personally think the the detection was good based on the file location in the system32 folder as a google search on the file name returned only 3 hits two of them in the avast forums (and the other virustotal detections). For a file to be legit and in the system32 folder I would expect many hits on a google search pointing me at the origin/program associated with the file.
The avast Win32:Trojan-gen is generic signature (the -gen at the end of the malware name), so that is trying to catch multiple variants of the same type of malware. So it isn’t detected by as a specific trojan.