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Create a backup of Avast4.ini
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Than change the mail section part in avast4.ini so that these settings are there:
[MailScanner]
Log=20
DefaultPopServer=
DefaultSmtpServer=
ShowTrayIcon=1
UseDefaultSmtp=0
AutoSetProtection=0
PopListen=
SmtpListen=
ImapListen=
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Setup the mail as if Avast isn’t there.
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Check if the mail is working
Let us know if it helps.