Interesting…

If I run the same program on Windows 2012 it always produces a pop-up and blocks running the program every time (if no exclusion is added) whether it is run from a network share or locally.

Doing the same on 2003 I sometimes get a pop-up but it always seems to run now whether it is local or from a network share.

I’m guessing it should always block on XP/2003 like it does on 2012 so something may be broken in avast when running on XP/2003. As avast say they support 2003 this may need to be investigated.