system
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elun,
I believe that you mean “Microsoft Outlook/Exchange” and Outlook Express (most likely version 5 or 6)
Avast will work with either. For it to scan MS Outlook, you will need to have the MS plugin installed. Check this by right clicking on the A ball in the tray and opening the On Access Protection Module. See if MS Exchange shows.
IF not, then go to Start/Settings/Control Panel, Add/Remove, and doubleclick on Avast. You will be given an option to Update/Change. Open up this option and select Change. Check the box next to MS Outlook/Exchange and hit Apply and OK to install MS Exchange plugin.
When this is done, run the Mail Protection Wizard from the Start/Programs/Avast.
When you run the MPW, check the box to protect all accounts.
Avast should check either program dependent upon which one opens.
Good luck.
If any further problems, come back here and let me know.