So outlook emails get blocked even if you have Mail Shield disabled? And this is only for incoming emails? Which Avast version do you have (Menu> About)?
What error message to get in outlook? Please provide a screenshot. https://support.avast.com/en-ww/article/Create-screenshot
Can you please disable IPv6 and let me know if that helps?
{From the Start menu, select Control Panel > Open Network and Sharing Center >
On the left, select Change adapter settings > Right-click the connection for which you want to disable IPv6, and select Properties.
Uncheck Internet Protocol Version 6 (TCP/IPv6) and click OK.}